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One of the simplest and best known kinds of crystal is the ionic salt (离子盐), of which a typical example is sodium chloride, or o
One of the simplest and best known kinds of crystal is the ionic salt (离子盐), of which a typical example is sodium chloride, or o
admin
2020-08-17
6
问题
One of the simplest and best known kinds of crystal is the ionic salt (离子盐), of which a typical example is sodium chloride, or ordinary table salt. The fundamental components of an ionic salt are ions: atoms or molecule that have become electrically charged by gaining or losing one or more electrons. In forming sodium chloride, for example, sodium atoms give up an electron (thereby becoming, positively charged) and chlorine atoms gain an electron (thereby becoming, negatively charged). The ions are attracted to one another by their opposite charges, and they stack together compactly, like tightly packed spheres.
Recently, scientists at Michigan State University created a new kind of crystal called an electride. In electrides, the anions (negative ions) are completely replaced by electrons, which are trapped in naturally formed cavities within a framework of regularly stacked cations (positive ions). Electrides are the first examples of ionic salts in which all these anionic sites are occupied solely by electrons.
Unlike other types of anions, anionic electrons do not behave as if they were
simple charged spheres.
In particular, because of their low mass and their tendency to interact with one another over great distances, they cannot be "pinned down" to any one location. Instead, they wander close to and among the atoms lining the cavity and interact with electrons in nearby cavities, perhaps changing places with them.
The properties of an electride depend largely on the distance between the cavities that hold trapped electrons. When the trapped electrons are far apart, they do not interact strongly, and so behave somewhat like an array of isolated negative charges. When they are closer together, they begin to display properties associated with large ensembles of identical panicles. When they are still closer, the ensemble properties dominate and the electrons "delocalize": they are no longer lightly bound within individual cavities but are more or less free to pass through the spaces within the frame-work of positive ions.
By synthesizing electrides from a variety of materials, one can vary the geometry of the anionic cavities and their relation to the surrounding cations. The resulting properties may make it possible for electrides to become a basis for economically useful new materials and devices. For instance, because the electrons in some electrides are very weakly bound, these crystals could be effective as photosensitive detectors, in which an impinging photon liberates an electron, resulting in a small electric current. The same weak binding could also make electrides useful in solar-energy converters and as cathodes in batteries. One obstacle is the tendency of electrides to decompose through reaction with air and water. Researchers are seeking ways to increase their stability.
It can be inferred from the passage that anions behaving as "simple charged spheres" could be expected to________.
选项
A、remain fixed relative to their cations
B、move freely in and out of their cavities
C、respond to photons by liberating electrons
D、readily lose electrons and become positively charged
答案
A
解析
判断推理题。根据simple charged spheres定位到第三段第一句。该句指出,阴离子电子与一般的阴离子不同,第二、三句指出,阴离子电子不会“固定”在一个地方,而是会与空穴中的电子相互作用,改变位置。由此可知,一般的阴离子不会变动位置,A项与原文一致,故为答案。
转载请注明原文地址:https://kaotiyun.com/show/S0ra777K
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